Favorite Polymer
Demonstrations
for Middle School Teachers
by Wayne Goates, from Goddard, KS and "Booger Hollow Science"
A. Shell Game
Materials: sodium polyacrylate (diaper absorber powder), water,
3 opaque cups, sodium chloride
Sodium polyacrylate can be used to do a revised version of the old
shell game where students must pick the cup that has the pea under
it. Have three cups (right side up) on the demo table. One cup should
contain a couple of scoops of sodium polyacrylate. Tell your students
to watch carefully. Pour about 100 mL of water into that cup and then
switch the cups around and have students guess which cup contained
the water. When students guess the correct cup, turn the cup upside
down and show that no water runs out. Add salt to show students that
in fact there was water but it was in a gel form as the chemical absorbed
the water. Sodium chloride releases the water from the gel.
B. Magic Sand
Materials: fine white sand, Scotch-Guard water-repellent (spray),
oven or Toaster Oven
Magic Sand or Mystic Sand is sand that has been treated with a colored
dye and coated with finely divided hydrophobic silicon coating. Due
to the coating, it can be used to form underwater towers or columns
or designs, and then be removed. The sand will be completely dry.
Spraying oven-dried sand one hour at 250° F with a water-repellent
material such as Scotch-Guard will make a magic sand type of material.
C. Melting Money
Materials: Melting Money (Flinn AP8678), water, container
Melting Money and Melting Memos, marketed by So Much Fun, are paper
items that dissolve when placed in water. The paper is composed of
carboxymethylcellulose (starch) with 20% or less cellulose. This material
has been used by organizations such as the CIA for secret or sensitive
documents that can easily be destroyed by wetting with water. A number
of toys using this are Trash Bag Bunch, the wrapper of Hot Wheels
Revealers, Magic Nursery Dolls, and their Bye-Bye Diapers.
D. Density of HDPE and LDPE
Materials: large glass cylinder, alcohol and water solution, samples
of HDPE and LDPE
Since its accidental discovery in 1933, polyethylene (PE) has become
the worlds largest poundage plastic. The difference in density
can be easily, quickly, and clearly demonstrated in the classroom
by the use of a large glass cylinder. Fill the cylinder with alcohol-water
solution. A one-liter cylinder filled with 50-50 volume of 95% ethyl
alcohol (or methyl alcohol) and water works well. When two half-dollar
sized pieces of high density polyethylene (HDPE) and low density polyethylene
(LDPE) are added to the solution in the cylinder, the HDPE will sink
while the LDPE will remain floating. (HDPE is used to make plastic
grocery sacks and butter containers and LDPE is used to make fresh
produce bags at the grocery store or squeezeable bottles. Check the
recycle codes.) The PE samples can also be cut to the form the letters
"H" and "L" for high and low. Make sure you cut
the width of the letters to be about the diameter of the cylinder
so that the letters will remain upright as they position themselves
in the cylinder. The solution can be kept indefinitely in a closed
container and reused many times. The HDPE molecules are linear and
can be packed closely together making the plastic opaque and non-waxy.
The LDPE molecules are branched chains with less packing and so the
plastic has greater transparency, flexibility and waxiness.
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E. The Fireproof Balloon
Materials: round balloons, water, long matches or Booger Hollow
Light Stick or candle on a meter stick
Balloons are fragile and must be kept from sharp objects and
flames! A fire can weaken the rubber and cause it to burst.
However, in this demonstration, one will find that a flame held
directly under a balloon will not break it. Inflate one balloon
with air and tie it closed. Place 60 ml of water in the other
balloon and then inflate it with air and tie it closed. Activate
the flame to touch the air filled balloon. What happens? The
balloon breaks because the rubber becomes hot and the bonds
break as the hot air inside the balloon increases the pressure
on the rubber. Activate another flame and hold it directly under
the water filled balloon. Allow the flame to touch the balloon.
What happens? The balloon does not break because the water is
absorbing heat and not the rubber. Water is a good absorber
of heat or it has a high heat capacity. It takes 10 times as
much heat to raise the temperature of one gram of water 1°
C than it does to raise the temperature of one gram of iron
by the same amount. This is why it takes so long to bring a
teakettle of water to the boiling point. However, when water
cools, it releases all that stored heat. Land areas near oceans
and lakes stay warmer in the winter than areas at the same latitude
further inland for this same reason.
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F. The Booger Hollow Light Stick
Materials: one meter stick, two meters of surgical hose, BBQ
butane lighter with trigger, electrical tape
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Assembly: Using the electrical tape, secure the lighter to one end
of the meter stick. Thread the surgical hose through the trigger mechanism
of the lighter. Tie the ends of the hose together to make a loop that
can be stretched to hook onto the end of the meter stick. Turn the
lighter to the "on" position. Push (or pull) of the trigger
mechanism to activate a flame. Keep your finger on the trigger while
you stretch the surgical hose over the end of the meter stick. This
keeps the trigger depressed and allows you to control the flame at
a maximum distance of one meter.